According to valence shell electron pair repulsion rules (VSEPR - remember learning those in long-ago undergrad days?), what structure would you expect a compound with 10 Ge atoms around 1 Co? Distribute all those bonds equally and you'd get a bicapped square antiprism. But instead you get a nearly geometrically perfect pentagonal prism — even the Ge–Ge distances BETWEEN the pentagonal faces are nearly the same as those WITHIN the faces.
Wednesday, 7 October 2009
Highlights: Nanotube electrocatalysts, pentagonal prisms and corroding platinum
According to valence shell electron pair repulsion rules (VSEPR - remember learning those in long-ago undergrad days?), what structure would you expect a compound with 10 Ge atoms around 1 Co? Distribute all those bonds equally and you'd get a bicapped square antiprism. But instead you get a nearly geometrically perfect pentagonal prism — even the Ge–Ge distances BETWEEN the pentagonal faces are nearly the same as those WITHIN the faces.
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